姓 名:郑博拓
性 别:男
出生年月:1994
职 称:讲师
学科专长:高分子化学与物理
个人简介:
郑博拓,男,博士研究生,浙江大学高分子科学与工程学系毕业。2021年作为引进人才进入福建师范大学化学与材料学院。主要研究方向为逆硫化合成高性能聚硫材料、功能纳米颗粒的制备及其在聚合物共混改性中的应用、新型聚氨基酸的合成与应用。迄今,已在Biomacromolecules、Macromolecules、Comm. Chem.、Macromol. Rapid Commun.等期刊发表论文14篇。
教育经历:
2016.09–2021.06 浙江大学 高分子化学与物理专业 博士 导师:凌君 教授、沈之荃 院士
2012.09–2016.06 浙江大学 高分子材料与工程专业 本科
科研与学术工作经历:
2021.09–今 福建师范大学化学与材料学院 讲师
研究领域:
新型聚硫材料的合成与性能研究,功能化纳米颗粒的合成及聚合物共混改性
教学情况:本科生课程《有机合成设计》、《聚合物改性原理》。
代表性论文/著作:
1. B. Zheng; T. Bai; X. Tao; H. Schlaad; J. Ling. Identifying the Hydrolysis of Carbonyl Sulfide as a Side Reaction Impeding the Polymerization of N-Substituted Glycine N-Thiocarboxyanhydride. Biomacromolecules 2018, 19 (11), 4263-4269.
2. B. Zheng; T. Bai; J. Ling; J. Sun. Direct polymerization of N-Thiocarboxyanhydride towards poly(amino acid)s bearing unprotected carboxyl group. Commun. Chem. 2020, 3, 144.
3. B. Zheng; S. Xu; X. Ni; J. Ling. Understanding Acid-Promoted Polymerization of the N-Substituted Glycine N-Thiocarboxyanhydride in Polar Solvents. Biomacromolecules 2021, 22 (4), 1579.
4. 郑博拓, 陶鑫峰, 凌君. 伯胺引发 NNTA 开环聚合对水的耐受性研究. 高分子学报2017 (1), 72-79.
5. B. Zheng; T. Bai; J. Ling. R. An Inspection into Multifarious Ways to Synthesize Poly(amino acid)s.Macromol. Rapid Commun. 2021, 42, 2100453.
6. X. Tao; B. Zheng; H. R. Kricheldorf; J. Ling. Are N-substituted glycine N-thiocarboxyanhydride monomers really hard to polymerize?, J. Polym. Sci., Part A: Polym. Chem. 2017, 55 (3), 404.
7. X. Tao; B. Zheng; T. Bai; B. Zhu; J. Ling. Hydroxyl Group Tolerated Polymerization of N-Substituted Glycine N-Thiocarboxyanhydride Mediated by Aminoalcohols: A Simple Way to α-Hydroxyl-ω-aminotelechelic Polypeptoids, Macromolecules 2017, 50 (8), 3066.
8. X. Tao; B. Zheng; T. Bai; M.-H. Li; J. Ling. Polymerization of N-Substituted Glycine N-Thiocarboxyanhydride through Regioselective Initiation of Cysteamine: A Direct Way toward Thiol-Capped Polypeptoids, Macromolecules 2018, 51 (12), 4494-4501.
9. J. Cen; B. Zheng; Y. Yang; J. Wu; Z. Mao; J. Ling; G. Han. Ag@ polyDOPA-b-polysarcosine hybrid nanoparticles with antimicrobial properties from in-situ reduction and NTA polymerization. Eur. Polym. J. 2019, 121, 109269.
10. T. Bai; B. Zheng; J. Ling. DFT Studies on the Synthesis of Poly (a-amino acid) s via the Amine-mediated Ring Opening Polymerizations of N-carboxyanhydrides and N-thiocarboxyanhydrides.Front. Chem. 2021, 9, 134.
11. T. Bai; P. Zhou; Z. Li; B. Zheng; J. Ling, Seeding Crystals, Harvesting Polypeptides: Preparing Long Chiral-Sequence Controlled Polypeptides by Interlocked Polymerization in Cocrystals (iPiC) of N-Thiocarboxyanhydride (NTA) at Room Temperature. Macromolecules 2021, 54 (14), 6691.
12.T. Bai; B. Shen; D. Cai; Y. Luo; P. Zhou; J. Xia; B. Zheng; K. Zhang; R. Xie; X. Ni. Understanding ring-closing and racemization to prepare α-amino acid NCA and NTA monomers: A DFT study. PCCP 2020, 22, 14868.
邮箱:zhengbotuo@fjnu.edu.cn/147880727@qq.com
通讯地址:福建省福州市上三路8号,福建师范大学化学与材料学院东楼305室
邮编:350007