黄秋锋个人简介:教授,博士生导师。2001年毕业于福建师范大学化学系,同年考入本校硕士研究生,师从林深教授,从事ZSM-5分子筛负载铜铋复合氧化物催化剂的制备及催化合成丁炔二醇的研究。2004-2008年清华大学化学系华瑞茂教授组攻读博士,从事过渡金属配合物催化活化CO及其催化定向转化反应。2008-2010年美国佛蒙特大学Matthias Brewer教授组从事博士后工作,从事新型环断裂反应及重排在天然产物Demissidine的全合成应用的研究。2019-2020年德国哥廷根大学化学系Lutz Ackermann组进行访问研究,从事有机电化学合成吲哚并环化合物的研究。2010年6月-至今在福建师范大学化学与材料学院工作,福建师范大学第二批优秀青年骨干教师,入选福建省教育厅新世纪人才支持计划项目。近几年年主持国家自然科学基金2项,参与一项国家自然科学基金(排名第二),一项国家自然科学基金重点项目(排名第三),主持福建省自然科学基金3项,福建省教育厅项目3项。近几年主要从事催化活化化学键及其转化反应研究。主要包括:1)清洁能源转化:研究过渡金属配合物催化活化CO及其催化定向转化反应,建立原子经济性合成羰基类化合物的新型催化剂体系。2)绿色催化:①研究过渡金属配合物作为催化剂催化C-H键官能团化反应的绿色合成方法。②有机电化学合成。
联系方式:qiufenghuang@fjnu.edu.cn
通信地址:福建师范大学仓山校区化学与材料学院东楼503室 邮 编:350007
教育及工作经历:
1997.09-2001.07 福建师范大学化学系,获学士学位
2001.09-2004.07 福建师范大学化学系,获硕士学位,导师:林深教授
2004.09-2008.01 清华大学化学系,获理学博士学位,导师:华瑞茂教授
2008.04-2010.04 美国佛蒙特大学化学系博士后,合作导师:Matthias Brewer
2019.11-2020.11 德国哥廷根大学化学系,访问学者,合作者:Lutz Ackermann
2010.06-现在 福建师范大学化学与材料学院
社会兼职:
中国化学会会员,福建省化学会监事
国家自然科学基金通讯评审
美国化学会(Org. Lett., J. Org Chem),德国化学会(Angew. Chem. Int. Ed., Chem- Eur J., Chem- Asian J., Adv. Synth. Catal.),英国皇家化学会(Chem. Sci., Chem Commun、New J. Chem)和App. Orgnomet. Chem., Tetrahedron Lett., Synlett,有机化学等国际期刊论文审稿人
科研项目:
1.(主持)国家自然科学基金面上项目:基于2-芳基吲哚的催化环化反应合成吲哚并中环化合物的方法学研究,2019.01-2022.12
2.(主持)福建省自然科学基金项目:催化环化反应合成稠多环吲哚化合物,2020.08-2023.8
3.(主持)福建省自然科学基金项目:氧气气氛中两分子C-H键脱氢偶联反应及其应用,2017.04-2020.3
4.(主持)福建省教育厅新世纪人才支持计划项目:过渡金属催化C-H键的羰基化反应,2017. 01-2019. 12
5.(主持)高校自然基金青年重点项目:基于一氧化碳的过渡金属催化C-H键羰基化反应构建C-C(=O)-C的研究,2017. 01-2019. 12
6.(主持)国家自然科学基金青年基金:钯-多金属氧酸盐体系催化C-H键官能团化构建C-C、C-N键,2012. 01-2014. 12
教学情况:
博士研究生和硕士研究生:催化研究与方法
代表性论文著作:
1.Yumeng Yuan+, Jinlan Zhu+, Zhongyuan Yang, Shao-Fei Ni*, Qiufeng Huang*, Lutz Ackerman*, Scalable Rhodaelectro-Catalyzed Expedient Access to Seven-membered Azepino[3,2,1- hi]indoles via [5+2] C-H/N-H Annulation, CCS Chemistry, 2022, DOI: 10.31635/ccschem.022.202101654
2.Guoshuai Pan, Leipeng Lu, Weihui Zhuang, Qiufeng Huang*, Synthesis of Indole-Fused Six , Seven , or Eight-Membered N,O-Heterocycles via Rhodium-Catalyzed NH-Indole-Directed C−H Acetoxylation/Hydrolysis/Annulation, The Journal of Organic Chemistry, 2021, 86, 16753-16763.
3.Weihui Zhuang, Jiaqi Zhang, Yanping Zheng, Qiufeng Huang*, Rhodium-Catalyzed Oxidative Annulation of 2- or 7-Arylindoleswith Alkenes/Alkynes UsingMolecular Oxygen as the SoleOxidant Enabled by Quaternary Ammonium Salt, Molecules, 2021, 26, 5329.
4.Yao Qin, Weihui Zhuang, Xiemin Guo, Xiaofeng Zhang, Qiufeng Huang*, Rhodium-catalyzed direct C-H amination of 2-arylindoles and 7-arylindoles with free amines, Tetrahedron Letters, 2021, 62, 152686.
5.Weihui Zhuang, Yuan-Zheng Cheng, Xu-Lun Huang, Qiufeng Huang*, Xiao Zhang*, Visible-light induced divergent dearomatization of indole derivatives: controlled access to cyclobutane-fused polycycles and 2-substituted indolines, Organic Chemistry Frontiers, 2021, 8, 319-325.
6.Weihui Zhuang, Xiaofeng Zhang*, Qiufeng Huang*, Recent advances in cross-dehydrogenative-coupling reactions using molecular oxygen as the sole oxidant, Chinese Journal of Organic Chemistry, 2021, 41, 529-542.
7.Yumeng Yuan, Xiemin Guo, Xiaofeng Zhang*, Buhong Li, Qiufeng Huang*, Access to 5H-benzo[a]carbazol-6-ols and benzo[6,7]cyclohepta[1,2-b]indol-6-ols via rhodium-catalyzed C–H activation/carbenoidinsertion/aldol-type cyclization, Organic Chemistry Frontiers, 2020, 7, 3146-3159.
8.Yumeng Yuan, Guoshuai Pan, Xiaofeng Zhang, Qiufeng Huang*, One pot synthesis of pyrrolo[3,2,1-de]phenanthridines from 7-phenylindoles via tandemC–H olefination/aza-Michael addition, Organic Chemistry Frontiers, 2020, 7, 53-63.
9.Guoshuai Pan, Yumeng Yuan, Lv Su, Xiaofeng Zhang, Qiufeng Huang*, Efficient synthesis of 2-amino-3-methylenephthalimindes by a palladium-catalyzed intramolecular aminocarbonylation, Synthetic Communications, 2020, 50, 1892-1898.
10.Yumeng Yuan, Guoshuai Pan, Xiaofeng Zhang, Buhong Li, Shengchang Xiang, Qiufeng Huang*, Rhodium-Catalyzed regioselective C-H activation/1,8-diazabicyclo[5.4.0]undec-7-ene-catalyzed intramolecular amidationof 7 phenylindoles in one pot, The Journal of Organic Chemistry, 2019, 84, 14701-14711.
11.Anyi Liu, Qingshuai Han, Xiaofeng Zhang, Buhong Li, Qiufeng Huang*. Transition-Metal-Controlled Synthesis of 11H-Benzo[a]carbazoles and 6-Alkylidene-6H-isoindo[2,1-a]indoles via Sequential Intermolecular/Intramolecular Cross-Dehydrogenative Coupling from 2-Phenylindoles, Organic Letters,2019, 21, 6839-6843.
12.Qingshuai Han, Xiemin Guo, Ziyuan Tang, Lv Su, Zizhu Yao, Xiaofeng Zhang, Shen Lin, Shengchang Xiang,Qiufeng Huang.*Rhodium-catalyzed regioselective ortho C-H olefination of 2-arylindoles via NH-indole-directed C-H bond cleavage, Advanced Synthesis& Catalysis, 2018, 360,972-984.
13.Guoshuai Pan, Kongchuan Wu, Zeying Deng, Xinyu Zhang, Xiaofeng Zhang, Shen Lin, Qiufeng Huang*. Chinese Journal of Organic Chemistry, 2018, 38, 2076-2084.
14.Xiemin Guo, Qingshuai Han, Ziyuan Tang, Lv Su, Xinyu Zhang,Xiaofeng Zhang, Shen Lin,Qiufeng Huang*. Rhodium-catalyzed NH-indole-directed ortho C-H coupling of 2-arylindoles with diazo compounds via metal carbene migratory insertion,Tetrahedron Letters, 2018,59, 1568-1572.
15.Xinyu Zhang, Lv Su, Lin Qiu, Zhenwei Fan, Xiaofeng Zhang, Shen Lin,Qiufeng Huang*.Palladium-catalyzed C–H olefination of uracils andcaffeines using molecular oxygen as the soleoxidant, Organic & Biomolecular Chemistry, 2017, 15, 3499-3506.
16.Lv Su, Hanbing Xiao, Yumeng Yuan, Xiaofeng Zhang, Shen Lin, Qiufeng Huang*.Palladium-catalyzed C-H alkoxycarbonylation of caffeines: synthesisof 8-ester-substituted caffeines, Chinese Journal of Organic Chemistry, 2017, 37, 630-635.
17.Qiufeng Huang*, QingShuai Han, Shurong Fu, Zizhu Yao, Lv Su, Xiaofeng Zhang, Shen Lin*, Shengchang Xiang. Rhodium-Catalyzed NH-Indole-Directed C−H Carbonylation with Carbon Monoxide: Synthesis of 6H Isoindolo[2,1 a]indol-6-ones, The Journal of Organic Chemistry, 2016, 81, 12135-12142.
18.Qingshuai Han, Shurong Fu, Xiaofeng Zhang, Shen Lin Qiufeng Huang*. Facile approaches toward the synthesis of 6H-isoindolo[2,1-a]indol-6-ones via palladium-catalyzed carbonylation with carbon monoxide, Tetrahedron Letters, 2016,57, 4165-4169.